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Triphenylphosphine Oxide(TPPO) CAS No.:791-28-6

Triphenylphosphine Oxide (TPPO), with the chemical formula (C₆H₅)₃PO or C₁₈H₁₅OP and molecular weight 278.29 g/mol, is a stable organophosphorus compound. It appears as a white to off-white crystalline solid and is a common byproduct in reactions involving triphenylphosphine, such as the Wittig and Mitsunobu reactions. TPPO is valued for its versatility as a ligand, catalyst, and additive in various industrial and research applications.
  • aozun

  • Triphenylphosphine oxide

  • White crystalline powder

  • 791-28-6

  • C18H15OP

  • 278

  • 212-338-8

  • slightly soluble in water

Availability:

Product Description

Key Properties

  • Appearance: White to cream-colored crystalline powder

  • Melting Point: 154–158°C

  • Boiling Point: ~360°C

  • Density: ~1.212 g/cm³

  • Solubility: Soluble in organic solvents like chloroform, acetone, aromatic hydrocarbons, and ether; slightly soluble in ethanol; poorly soluble in water

  • Stability: Chemically stable with strong P=O bond

High-purity grades (typically ≥99%) are available for technical and specialty uses.

Main Applications

  • Organic Synthesis: Catalyst or Lewis base in epoxidations, Michael additions, coupling reactions, and other transformations.

  • Polymer & Materials Science: Flame retardant additive in plastics and polymers; curing agent for epoxies.

  • Coordination Chemistry: Ligand for metal complexes in catalysis and material synthesis.

  • Electronics & Energy: Additive in perovskite solar cells, OLEDs, and redox flow batteries for defect passivation and performance enhancement.

  • Analytical Chemistry: Used in extraction and determination of metals (e.g., cadmium, mercury).

  • Other: Crystallization aid, anti-fouling agent, and intermediate in phosphorus chemistry.

Quality Standards

Available in high-purity powder form with low impurities, suitable for pharmaceutical, electronic, and industrial applications.

Safety Information

Generally stable but handle with standard laboratory precautions. Avoid inhalation of dust and contact with eyes or skin. Use appropriate PPE and refer to the SDS for detailed handling, storage, and disposal recommendations.

Frequently Asked Questions (FAQs)

What is the CAS number for Triphenylphosphine Oxide?

791-28-6.

What is the chemical formula?

(C₆H₅)₃PO or C₁₈H₁₅OP.

What is TPPO commonly known as?

Triphenylphosphine oxide (TPPO).

Is TPPO soluble in water?

Poorly soluble in water but highly soluble in many organic solvents.

What are the main uses of TPPO?

Organic synthesis catalysis, flame retardants, metal coordination, perovskite solar cells/OLEDs, and analytical chemistry.

Why is TPPO important in organic chemistry?

It is a stable byproduct of key reactions (e.g., Wittig) and can be used as a catalyst, ligand, or recycled in advanced processes.

How should it be stored?

In a cool, dry place away from strong oxidizing agents, in tightly closed containers.

Contact Us

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