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Sodium Hydrosulfide (NaHS)

Sodium Hydrosulfide (NaSH) is a high-purity inorganic sulfur compound widely used in mining, chemical manufacturing, leather processing, and water treatment industries. It is valued for its strong reducing properties, high solubility in water, and ability to release hydrogen sulfide in controlled reactions, making it essential for metal recovery, chemical synthesis, and industrial applications.
  • 16721-80-5

  • HNaS

  • 56.06

  • 240-778-0

Availability:

Product Description

What Is Sodium Hydrosulfide?

Sodium hydrosulfide, also called sodium hydrogen sulfide or sodium bisulfide, is an inorganic sulfur compound with the formula NaHS. It is used as a sulfiding, reducing and process reagent in mining, leather, pulp and paper, chemical manufacturing and selected wastewater-treatment applications.

Commercial NaHS is commonly supplied as hydrated flakes or an aqueous solution. The required form, concentration and impurity limits should be confirmed before ordering.

AOZUN supports sodium hydrosulfide sourcing for qualified industrial applications. Grade, specification, packaging and transport requirements are confirmed at the quotation stage.

Which Sodium Hydrosulfide Form Do You Need?

Form

Typical commercial description

Purchasing consideration

Hydrated flakes

Commonly around 70% NaHS

Easier international packing and on-site solution preparation

Aqueous solution

Commonly supplied at approximately 20%–47%

Suitable for controlled pumping and closed process dosing

Application-specific grade

Low-iron or controlled-impurity material

Used when color, flotation performance or downstream purity is critical

A “70% NaHS” product normally refers to hydrated flakes, not a conventional 70% aqueous solution. Buyers should confirm whether the quoted percentage is an active-content specification or a solution concentration.

Sodium Hydrosulfide Identification and Properties

Item

Information

Product name

Sodium hydrosulfide

Alternative names

Sodium hydrogen sulfide, sodium bisulfide, sodium sulfhydrate

Abbreviation

NaHS

Molecular formula

NaHS

Molecular weight

56.06 g/mol

Anhydrous CAS number

16721-80-5

Hydrate CAS number

207683-19-0

Chemical class

Inorganic sulfide

Flake appearance

Commonly yellow to brown flakes

Solution appearance

Colorless, yellow, green or brown aqueous liquid

Main function

Sulfiding, reducing and industrial process reagent

Color can vary with concentration, iron, polysulfides, oxidation and storage conditions. The agreed specification and batch COA should govern acceptance.

What Is Sodium Hydrosulfide Used For?

Mineral Processing and Flotation

NaHS is used as a sulfidizing and flotation reagent in selected copper, molybdenum and other mineral-processing circuits. Dosage should be established through ore-specific flotation testing.

Leather Processing

Sodium hydrosulfide may be used as a process aid in dehairing and related tannery operations. Closed dosing and hydrogen-sulfide controls are essential.

Pulp and Paper

NaHS is used as a sulfur-containing process chemical in selected pulp and cellulose operations.

Dyes and Textile Processing

It can be used in the manufacture or application of sulfur dyes and in other controlled reducing processes.

Wastewater and Metal Precipitation

NaHS may be used to precipitate selected dissolved metals as metal sulfides. Treatment must be designed to prevent excess sulfide and hydrogen-sulfide release.

Chemical Manufacturing

It can serve as a sulfur source, reducing reagent or intermediate in the production of sulfur-containing chemicals.

Which Sodium Hydrosulfide Specifications Matter Most?

The correct NaHS grade depends on active content, process sensitivity, dosing equipment and acceptable impurity levels.

Sodium hydrosulfide flakes and sealed solution samples with closed dosing and gas monitoring equipment

Quality attribute

Why it matters

NaHS assay

Determines active reagent dosage

Sodium sulfide, Na₂S

Affects alkalinity, sulfide balance and process selectivity

Sodium carbonate, Na₂CO₃

May influence alkalinity and reagent consumption

Iron

Can affect product color and sensitive downstream processes

Insoluble matter

May block filters, pumps or dosing nozzles

Oxidation products

Thiosulfate, sulfite or sulfate can indicate air oxidation

Moisture or crystal water

Important for interpreting flake assay

Specific gravity

Supports concentration control for liquid products

pH

Helps monitor solution condition and H₂S-release risk

Appearance and color

Useful for detecting oxidation, contamination or batch changes

Specifications must state whether results are reported on an as-received, dry or active basis. Typical values are not substitutes for guaranteed limits.

How Is NaHS Different from Similar Sodium Chemicals?

Product

Formula

Main distinction

Sodium hydrosulfide

NaHS

Industrial sulfiding reagent and hydrosulfide source

Sodium sulfide

Na₂S

Different sulfide-to-sodium ratio and alkalinity

Sodium hydrosulfite

Na₂S₂O₄

Also called sodium dithionite; a different reducing chemical

Sodium bisulfite

NaHSO₃

Sulfur-oxygen salt used as a reducing or preservative reagent

“Sodium hydrosulfide” and “sodium hydrosulfite” are not interchangeable. Every inquiry should include the formula NaHS and the appropriate CAS number.

Packaging, Storage and Safe Handling

NaHS flakes are hygroscopic and can oxidize when exposed to air. Store them in tightly sealed, moisture-resistant packaging in a cool, dry and well-ventilated area.

NaHS solutions require compatible, corrosion-resistant tanks, piping, valves and pumps. Closed transfer and controlled ventilation are strongly recommended.

Never mix sodium hydrosulfide with acids. Acid contact or a significant reduction in pH can release highly toxic hydrogen sulfide gas.

Hydrogen sulfide may accumulate in tanks, process enclosures and low areas. Its odor must not be used as a safety warning because the sense of smell can rapidly become unreliable. Suitable fixed or portable gas monitoring, ventilation and emergency procedures are required.

Always follow the current SDS, site risk assessment and applicable transport and workplace regulations.

Which Packaging Should Buyers Select?

Packaging depends on physical form, quantity, transport route and local regulations.

Possible commercial formats include:

  • Moisture-resistant bags for flakes

  • Approved drums for solid product

  • Compatible drums or IBCs for qualifying solutions

  • Tank trucks, tank containers or other bulk systems for solution grades

Final packaging availability must be confirmed with the quotation. Transport classification can differ by concentration, hydration and product form.

Which Documents Should a NaHS Supplier Provide?

Depending on the destination and application, buyers may request:

  • Batch-specific Certificate of Analysis

  • Safety Data Sheet

  • Technical Data Sheet

  • Active NaHS and impurity test methods

  • Country-of-origin information

  • Manufacturing or retest date

  • Packaging specification

  • Dangerous-goods declaration

  • Transport classification and shipping documents

  • Application-specific iron or heavy-metal data

Why Source Sodium Hydrosulfide from AOZUN?

AOZUN helps buyers define the required NaHS form, active content, sodium-sulfide limit, carbonate limit, iron requirement, packaging and destination before quotation.

Availability and specifications are confirmed according to the application and current supply conditions. COA, SDS and available shipping documents can be requested for technical review.

Frequently Asked Questions About Sodium Hydrosulfide

Is sodium hydrosulfide organic or inorganic?

It is an inorganic sulfide salt composed of sodium and hydrosulfide ions.

Is NaHS a fine chemical or an intermediate?

NaHS is primarily a bulk inorganic industrial chemical and process reagent. It can also be classified as a chemical intermediate, but it is not normally considered a fine chemical.

Are sodium hydrosulfide and sodium hydrogen sulfide the same?

Yes. Both names generally refer to NaHS.

Is sodium hydrosulfide the same as sodium sulfide?

No. Sodium hydrosulfide is NaHS, while sodium sulfide is Na₂S. Their active content, alkalinity and application behavior differ.

Why are commercial NaHS flakes approximately 70%?

Commercial flakes are commonly supplied as a hydrated material containing crystal water. The NaHS assay is therefore lower than that of theoretical anhydrous NaHS.

Can NaHS release hydrogen sulfide?

Yes. Contact with acids or a decrease in pH can release toxic H₂S gas. Closed handling, gas monitoring and suitable ventilation are essential.

What information should be included in an NaHS inquiry?

Specify flakes or solution, required assay, Na₂S limit, Na₂CO₃ limit, iron limit, quantity, packaging, application and destination.

Request a Quote for Sodium Hydrosulfide

Please provide:

  • Required form: flakes or solution

  • Required NaHS concentration

  • Na₂S, Na₂CO₃ and iron limits

  • Intended application

  • Required quantity and packaging

  • Destination country and port

  • Required technical and transport documents

Contact AOZUN to discuss sodium hydrosulfide specifications, packaging, documentation and current availability.

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