16721-80-5
HNaS
56.06
240-778-0
| Availability: | |
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Product Description
Sodium hydrosulfide, also called sodium hydrogen sulfide or sodium bisulfide, is an inorganic sulfur compound with the formula NaHS. It is used as a sulfiding, reducing and process reagent in mining, leather, pulp and paper, chemical manufacturing and selected wastewater-treatment applications.
Commercial NaHS is commonly supplied as hydrated flakes or an aqueous solution. The required form, concentration and impurity limits should be confirmed before ordering.
AOZUN supports sodium hydrosulfide sourcing for qualified industrial applications. Grade, specification, packaging and transport requirements are confirmed at the quotation stage.
Form | Typical commercial description | Purchasing consideration |
|---|---|---|
Hydrated flakes | Commonly around 70% NaHS | Easier international packing and on-site solution preparation |
Aqueous solution | Commonly supplied at approximately 20%–47% | Suitable for controlled pumping and closed process dosing |
Application-specific grade | Low-iron or controlled-impurity material | Used when color, flotation performance or downstream purity is critical |
A “70% NaHS” product normally refers to hydrated flakes, not a conventional 70% aqueous solution. Buyers should confirm whether the quoted percentage is an active-content specification or a solution concentration.
Item | Information |
Product name | Sodium hydrosulfide |
Alternative names | Sodium hydrogen sulfide, sodium bisulfide, sodium sulfhydrate |
Abbreviation | NaHS |
Molecular formula | NaHS |
Molecular weight | 56.06 g/mol |
Anhydrous CAS number | 16721-80-5 |
Hydrate CAS number | 207683-19-0 |
Chemical class | Inorganic sulfide |
Flake appearance | Commonly yellow to brown flakes |
Solution appearance | Colorless, yellow, green or brown aqueous liquid |
Main function | Sulfiding, reducing and industrial process reagent |
Color can vary with concentration, iron, polysulfides, oxidation and storage conditions. The agreed specification and batch COA should govern acceptance.
NaHS is used as a sulfidizing and flotation reagent in selected copper, molybdenum and other mineral-processing circuits. Dosage should be established through ore-specific flotation testing.
Sodium hydrosulfide may be used as a process aid in dehairing and related tannery operations. Closed dosing and hydrogen-sulfide controls are essential.
NaHS is used as a sulfur-containing process chemical in selected pulp and cellulose operations.
It can be used in the manufacture or application of sulfur dyes and in other controlled reducing processes.
NaHS may be used to precipitate selected dissolved metals as metal sulfides. Treatment must be designed to prevent excess sulfide and hydrogen-sulfide release.
It can serve as a sulfur source, reducing reagent or intermediate in the production of sulfur-containing chemicals.
The correct NaHS grade depends on active content, process sensitivity, dosing equipment and acceptable impurity levels.
Quality attribute | Why it matters |
NaHS assay | Determines active reagent dosage |
Sodium sulfide, Na₂S | Affects alkalinity, sulfide balance and process selectivity |
Sodium carbonate, Na₂CO₃ | May influence alkalinity and reagent consumption |
Iron | Can affect product color and sensitive downstream processes |
Insoluble matter | May block filters, pumps or dosing nozzles |
Oxidation products | Thiosulfate, sulfite or sulfate can indicate air oxidation |
Moisture or crystal water | Important for interpreting flake assay |
Specific gravity | Supports concentration control for liquid products |
pH | Helps monitor solution condition and H₂S-release risk |
Appearance and color | Useful for detecting oxidation, contamination or batch changes |
Specifications must state whether results are reported on an as-received, dry or active basis. Typical values are not substitutes for guaranteed limits.
Product | Formula | Main distinction |
Sodium hydrosulfide | NaHS | Industrial sulfiding reagent and hydrosulfide source |
Sodium sulfide | Na₂S | Different sulfide-to-sodium ratio and alkalinity |
Sodium hydrosulfite | Na₂S₂O₄ | Also called sodium dithionite; a different reducing chemical |
Sodium bisulfite | NaHSO₃ | Sulfur-oxygen salt used as a reducing or preservative reagent |
“Sodium hydrosulfide” and “sodium hydrosulfite” are not interchangeable. Every inquiry should include the formula NaHS and the appropriate CAS number.
NaHS flakes are hygroscopic and can oxidize when exposed to air. Store them in tightly sealed, moisture-resistant packaging in a cool, dry and well-ventilated area.
NaHS solutions require compatible, corrosion-resistant tanks, piping, valves and pumps. Closed transfer and controlled ventilation are strongly recommended.
Never mix sodium hydrosulfide with acids. Acid contact or a significant reduction in pH can release highly toxic hydrogen sulfide gas.
Hydrogen sulfide may accumulate in tanks, process enclosures and low areas. Its odor must not be used as a safety warning because the sense of smell can rapidly become unreliable. Suitable fixed or portable gas monitoring, ventilation and emergency procedures are required.
Always follow the current SDS, site risk assessment and applicable transport and workplace regulations.
Packaging depends on physical form, quantity, transport route and local regulations.
Possible commercial formats include:
Moisture-resistant bags for flakes
Approved drums for solid product
Compatible drums or IBCs for qualifying solutions
Tank trucks, tank containers or other bulk systems for solution grades
Final packaging availability must be confirmed with the quotation. Transport classification can differ by concentration, hydration and product form.
Depending on the destination and application, buyers may request:
Batch-specific Certificate of Analysis
Safety Data Sheet
Technical Data Sheet
Active NaHS and impurity test methods
Country-of-origin information
Manufacturing or retest date
Packaging specification
Dangerous-goods declaration
Transport classification and shipping documents
Application-specific iron or heavy-metal data
AOZUN helps buyers define the required NaHS form, active content, sodium-sulfide limit, carbonate limit, iron requirement, packaging and destination before quotation.
Availability and specifications are confirmed according to the application and current supply conditions. COA, SDS and available shipping documents can be requested for technical review.
It is an inorganic sulfide salt composed of sodium and hydrosulfide ions.
NaHS is primarily a bulk inorganic industrial chemical and process reagent. It can also be classified as a chemical intermediate, but it is not normally considered a fine chemical.
Yes. Both names generally refer to NaHS.
No. Sodium hydrosulfide is NaHS, while sodium sulfide is Na₂S. Their active content, alkalinity and application behavior differ.
Commercial flakes are commonly supplied as a hydrated material containing crystal water. The NaHS assay is therefore lower than that of theoretical anhydrous NaHS.
Yes. Contact with acids or a decrease in pH can release toxic H₂S gas. Closed handling, gas monitoring and suitable ventilation are essential.
Specify flakes or solution, required assay, Na₂S limit, Na₂CO₃ limit, iron limit, quantity, packaging, application and destination.
Please provide:
Required form: flakes or solution
Required NaHS concentration
Na₂S, Na₂CO₃ and iron limits
Intended application
Required quantity and packaging
Destination country and port
Required technical and transport documents
Contact AOZUN to discuss sodium hydrosulfide specifications, packaging, documentation and current availability.