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Dioctyl Phthalate (DOP/DEHP) Plasticizer

Dioctyl Phthalate (DOP), also known as Di(2-ethylhexyl) phthalate (DEHP) or Bis(2-ethylhexyl) phthalate, is a widely used, cost-effective general-purpose plasticizer for polyvinyl chloride (PVC) and other polymers. With CAS Number 117-81-7 and molecular formula C₂₄H₃₈O₄, DOP provides excellent flexibility, durability, and processing characteristics to flexible vinyl products while maintaining low cost and broad compatibility.
  • transparent oily liquid

  • 117-84-0

  • C24H38O4

  • 390.56

  • 204-214-7

  • Insoluble in water

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Product Description

What Is Dioctyl Phthalate (DOP)?

Dioctyl Phthalate, commonly abbreviated as DOP, is the traditional market name for Bis(2-ethylhexyl) Phthalate or DEHP, CAS 117-81-7.

It is a colorless to pale-yellow oily liquid primarily used as a plasticizer in permitted industrial PVC formulations. DOP increases flexibility, supports processing and helps reduce the hardness of otherwise rigid polymer materials.

This page uses “DOP” to mean DEHP, CAS 117-81-7. Buyers should always confirm the CAS number because the name Dioctyl Phthalate can be ambiguous.

DOP Product Information

Item

Information

Product name

Dioctyl Phthalate

Preferred chemical name

Bis(2-ethylhexyl) Phthalate

Abbreviations

DOP, DEHP

CAS number

117-81-7

EC number

204-211-0

Molecular formula

C₂₄H₃₈O₄

Molecular weight

390.56 g/mol

Appearance

Colorless to pale-yellow oily liquid

Product type

Phthalate ester plasticizer

Primary use

Industrial flexible-PVC formulations

Does DOP Mean DEHP, DNOP or DOTP?

DOP is used inconsistently in international trade. The CAS number must be included in every specification, quotation, SDS and purchase order.

Product

Common name

CAS number

Chemical type

DOP/DEHP

Bis(2-ethylhexyl) Phthalate

117-81-7

Ortho-phthalate

DNOP

Di-n-octyl Phthalate

117-84-0

Linear ortho-phthalate

DOTP/DEHT

Bis(2-ethylhexyl) Terephthalate

6422-86-2

Terephthalate plasticizer

DOTP is not another name for DOP. It has a different molecular structure, regulatory profile and CAS number.

How Does DOP Plasticize PVC?

DOP molecules position themselves between PVC polymer chains and increase molecular mobility. This lowers material stiffness and helps produce a softer, more flexible compound.

The final performance depends on the DOP loading, PVC resin type, fillers, stabilizers, processing conditions and other additives.

Because DOP is not chemically bonded to PVC, migration, extraction and volatility should be evaluated for the intended service conditions.

DOP DEHP liquid plasticizer with PVC resin compounding equipment, flexible cable and vinyl sheet samples

Which DOP Specifications Should Buyers Compare?

Specification

Why It Matters

Ester content or purity

Confirms the principal product concentration

Color, APHA or Hazen

Important for light-colored and transparent PVC

Acidity

Helps assess process consistency and storage condition

Moisture

May affect PVC processing and compound quality

Density

Used for receiving and formulation calculations

Viscosity

Influences pumping, mixing and processing

Volume resistivity

Important for electrical cable compounds

Flash point

Relevant to storage and handling controls

Volatile matter

May affect processing loss and final performance

Regulatory status

Determines whether the intended market permits DEHP

A quotation should identify the test method and guaranteed limits rather than using only terms such as “high purity” or “premium grade.”

Where Is DOP Used?

Where regulations and customer specifications permit, DOP may be evaluated in:

  • Flexible PVC compounds

  • Industrial cable and wire insulation

  • PVC sheets and films

  • Synthetic leather

  • Industrial hoses

  • Flooring and coated fabrics

  • Plastisol formulations

  • Adhesives, sealants and selected coatings

  • Rubber and polymer-processing formulations

Suitability must be reviewed for each destination market and finished product. DOP should not automatically be promoted for toys, childcare products, food-contact materials, medical products or other restricted uses.

What Regulatory Checks Are Required?

DEHP is subject to significant restrictions in multiple markets.

In the European Union, DEHP is listed as a Substance of Very High Concern and is covered by REACH restrictions. EU RoHS restricts DEHP to 0.1% by weight in homogeneous materials within its scope, subject to applicable exemptions.

In the United States, children’s toys and childcare articles containing more than 0.1% DEHP in accessible component parts are prohibited.

Before ordering DOP, confirm:

  1. Destination country

  2. Finished-product category

  3. REACH and SVHC requirements

  4. RoHS requirements

  5. Customer restricted-substance list

  6. Required declarations and analytical reports

  7. Whether a non-phthalate or alternative plasticizer is required

A supplier declaration alone does not determine whether the finished product complies with local regulations.

DOP or an Alternative Plasticizer?

The appropriate plasticizer depends on regulatory requirements and performance targets.

Possible alternatives include DOTP, DINP, DPHP, TOTM and other non-phthalate plasticizers. They are not direct one-to-one replacements in every formulation.

Before changing plasticizers, compare:

  • Plasticizing efficiency

  • Low-temperature flexibility

  • Volatility

  • Migration and extraction resistance

  • Electrical properties

  • Plastisol viscosity

  • Processing temperature

  • Regulatory acceptance

  • Total formulation cost

Laboratory compounding and finished-product testing should be completed before commercial replacement.

Packaging, Storage and Handling

DOP may be supplied in drums, IBCs, flexitanks or bulk tankers, depending on quantity and destination.

Store the product in tightly closed, compatible containers in a cool and ventilated area. Protect it from contamination, strong oxidizing agents and uncontrolled discharge to the environment.

Use suitable gloves, protective clothing and eye protection. Prevent releases to drains, soil and waterways. Consult the current Safety Data Sheet before handling.

Why Source DOP from AOZUN?

AOZUN can support industrial buyers with:

  • Specification and grade matching

  • COA, SDS and technical-document support

  • Sample evaluation

  • Drum, IBC, flexitank or bulk-shipment coordination

  • Destination-market document review

  • Pre-shipment quality verification

  • Alternative plasticizer sourcing when required

Availability, regulatory documentation and guaranteed specifications should be confirmed for each order.

Dioctyl Phthalate FAQ

Is DOP the same as DEHP?

In most plasticizer markets, DOP refers to DEHP with CAS 117-81-7. The CAS number should always be confirmed because “dioctyl phthalate” can also be interpreted as DNOP.

Is DOP the same as DOTP?

No. DOP/DEHP is an ortho-phthalate, while DOTP is a terephthalate plasticizer with CAS 6422-86-2.

Is DOP an organic or inorganic chemical?

DOP is an organic ester. It is classified as a phthalate plasticizer and polymer additive.

Can DOP be used in toys or childcare products?

DEHP is restricted in toys and childcare products in major markets. The applicable regulations must be checked before any use or sale.

Can DOTP replace DOP directly?

Not automatically. The two products have different processing, migration and regulatory characteristics. A formulation trial is required.

Request a DOP Quotation

Contact AOZUN with the required CAS number, specification, application, packaging, order quantity, destination and regulatory-document requirements.

We can help verify the correct DOP/DEHP product and prepare a quotation for permitted industrial applications.

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