Uketshezi olukhanyayo olungenambala
109-99-9
C4H8O
72.11
203-726-8
Incibilika emanzini
| Ukutholakala: | |
|---|---|
Incazelo Yomkhiqizo
I-Tetrahydrofuran, evame ukufushaniswa njenge-THF, iwuketshezi oluphilayo olucacile, olungenambala, oluxubene namanzi olukhonjwe yi-CAS No. 109-99-9. Iyi-ether eyi-cyclic enamalungu amahlanu enenani ngenxa ye-solvency yayo eqinile, i-viscosity ephansi, ukuhwamuka okusheshayo kanye nekhono lokuncibilikisa uhla olubanzi lwama-polymers nezinhlanganisela ze-organic.
I-THF isetshenziswa kokubili njenge-solvent yenqubo nanjenge-chemical intermediate. Izicelo ezinkulu zifaka ukukhiqizwa kwe-PTMEG, ukwenziwa kwemithi kanye namakhemikhali amahle, ukusabela kwe-organometallic, okokunamathela, okunamathelayo, usimende we-PVC nokucutshungulwa kwe-polymer.
Sihlinzeka nge-Tetrahydrofuran ngokumelene nobumsulwa okuvunyelwene ngaso, umswakama, ukuqina, ukupakisha kanye nezidingo zemibhalo. Ukucaciswa komkhiqizo wokugcina kuqinisekiswa kwikhotheshini neqoqwana Isitifiketi Sokuhlaziya.
Igama lomkhiqizo: Tetrahydrofuran
Isifinyezo: THF
Inombolo ye-CAS: 109-99-9
Inombolo ye-EC: 203-726-8
Ifomula yemolekyuli: C₄H₈O
Isisindo se-molecule: 72.11 g/mol
Umndeni wamakhemikhali: I-ether yebhayisikili
Uhlobo lomkhiqizo: I-solvent ye-organic kanye namakhemikhali aphakathi
Ukubukeka: Uketshezi olucacile, olungenambala
Ukuhlonza ezokuthutha: UN 2056, Ikilasi lesi-3, Iqembu Lokupakisha II
Amanani alandelayo awulwazi olujwayelekile lwereferensi kunezicaciso zokuthengisa zenkontileka. Sebenzisa Ishidi Ledatha Yezobuchwepheshe elisebenzayo, Ishidi Ledatha Yezokuphepha kanye Nesitifiketi Sokuhlaziya lapho ufaneleka ukuthunyelwa.
Impahla |
Ireferensi evamile |
|---|---|
Igama lekhemikhali |
I-Tetrahydrofuran |
Elinye igama |
Oxolane |
Inombolo ye-CAS |
109-99-9 |
Ifomula yamangqamuzana |
C₄H₈O |
Isisindo samangqamuzana |
72.11 g/mol |
Ukubukeka |
Uketshezi olucacile, olungenambala |
Iphunga |
Iphunga elifana ne-ether |
Ibanga lokubilisa |
Cishe ku-65–67°C |
Iphuzu lokuqanda |
Cishe ku-−108.5°C |
Ukuminyana |
Cishe 0.88–0.89 g/cm³ |
Ukuncibilika kwamanzi |
Hlanganisa namanzi |
Iphoyinti le-Flash |
Ngaphansi kuka-0°C; inani lincike endleleni yokuhlola |
Ikilasi lamakhemikhali |
I-polar aprotic cyclic ether |
Ukucaciswa okuwusizo kwe-THF kufanele kufake okungaphezu kokuhlola kuphela. Imikhawulo efanele incike ekuphenduleni okuhlosiwe, uhlelo lwe-polymer, inqubo yokutakula kanye nezimo zokugcina.
Ipharamitha |
Kungani kubalulekile |
I-assay noma ubumsulwa |
Isiza ukulawula ukusebenza kwe-solvent, ukungaguquguquki kokusabela kanye namazinga ezinsalela |
Okuqukethwe kwamanzi |
Ibalulekile ekuphenduleni okuzwela umswakama, i-organometallic chemistry kanye nezinqubo ezikhethiwe ze-polymer |
I-BHT stabilizer |
Isiza ukwehlisa ukwakheka kwe-peroxide kodwa ingase ithinte izinhlelo zokusebenza ezizwela i-inhibitor |
Okuqukethwe kwe-Peroxide |
Kubalulekile ukugcina, ukudluliswa, ukugxila kanye nokuphepha kwe-distillation |
Umbala |
Isekela ukuhlolwa kwekhwalithi engenayo kanye nokuvumelana kwenqubo |
I-Acidity |
Ingase ibe nomthelela kuma-catalyst, ama-intermediate asebenzayo kanye nokwakheka okubucayi |
Izinsalela zokuhwamuka |
Ihambisana ne-electronics, umsebenzi wokuhlaziya kanye nokucubungula okuphezulu |
Ukuhlonza |
Iqinisekisa ubunikazi bempahla ngendlela yokuhlaziya okuvunyelwene ngayo |
Ukumuncwa kwe-UV noma ukudluliswa |
Okuvame ukudingeka ku-HPLC namabanga okuhlaziya |
Ukucaciswa kwenkontileka kufanele kuchaze indlela yokuhlaziya kanye nomkhawulo wezinombolo. Imiphumela etholwe ngamanzi ahlukene, i-peroxide noma izindlela zokuhlanzeka ingase ingaqhathanisi ngokuqondile.
I-THF eqinile iqukethe inani elilawulwayo le-inhibitor, ngokuvamile i-BHT, yokunciphisa ukwakheka kwe-peroxide phakathi nokugcinwa nokusabalalisa okuvamile.
Leli banga livame ukukhethelwa:
I-polymer kanye ne-resin processing
Izinamathiselo kanye nosimende we-PVC
I-General organic synthesis
Coatings kanye nokwenza umsebenzi
Izinhlelo ze-solvent zezimboni
Izinqubo lapho i-stabilizer eyamukelekayo
Ububanzi obudingekayo be-BHT kufanele bushiwo ekucacisweni kokuthenga kunokuba kuthathwe egameni lomkhiqizo.
I-Anhydrous THF ikhiqizwa noma iphathwe ukuze inikeze okuqukethwe kwamanzi aphansi okulawulwayo. Ngokuvamile kucatshangelwa ukusabela lapho umswakama ungadla ama-reagents, uvale ama-catalyst noma unciphise ukuguqulwa.
Ukusetshenziswa okungenzeka kuhlanganisa:
Ukusabela kwe-Grignard kanye ne-organometallic
Ukwenziwa kwemithi ezwela umswakama
Izinqubo zamakhemikhali ezisekelwe ku-Catalyst
I-polymerization ekhethekile
Ucwaningo kanye nezicelo zokuhlaziya
'I-Anhydrous' akusho ngokuzenzakalelayo 'i-inhibitor-free.' Abathengi kufanele bacacise kokubili okuqukethwe kwamanzi amaningi kanye nezinga elivunyelwe lokuzinzisa.
I-THF engena-inhibitor ihloselwe izinhlelo zokusebenza lapho i-BHT noma esinye isizinzisi singaphazamisa ukusabela, i-catalyst, ukuhlaziywa noma umkhiqizo wokugcina.
Ngenxa yokuthi i-THF engazinzile ingakha ama-peroxides ayingozi ngesikhathi sokuchayeka kumoya-mpilo nokukhanya, idinga ukupakishwa okulawulwa ngokucophelela, ukugcinwa, ukuhlolwa nokuphathwa kwempahla. Ukufaneleka kufanele kubuyekezwe ngabasebenzi abaqeqeshiwe bezobuchwepheshe nokuphepha ngaphambi kokuthenga.
Amabanga okuhlaziya angase ahlanganise izilawuli ezengeziwe zokumunca i-UV, izinsalela zokuhwamuka, amanzi, i-asidi kanye nokungcola komkhondo. Lawa mabanga enzelwe izinhlelo zokusebenza zaselabhorethri noma ezisekelwe kumathuluzi futhi akufanele akhethwe kuphela enanini lokuhlola.
I-THF ihlanganisa izakhiwo ezimbalwa ezenza kube usizo ekucubunguleni kwamakhemikhali ne-polymer:
Incibilikisa izinto eziningi eziphilayo ezitholakala ezindaweni ezishisayo nezingezona ze-polar.
Ixubene namanzi futhi iyahambisana nezinyibilikisi eziningi eziphilayo.
I-oxygen yayo ye-ether ingaxhumanisa nama-ion ensimbi nama-organometallic reagents.
Iphuzu layo lokubilisa eliphansi uma kuqhathaniswa lisekela ukususwa kwe-solvent kanye nokubuyiselwa.
I-viscosity yayo ephansi isekela ukuxuba, ukupompa kanye nokudluliswa okukhulu.
Ingancibilikisa noma ithambise ama-polymer akhethiwe, okuhlanganisa i-PVC nezinhlelo ezithile ze-polyurethane noma ze-resin.
Lezi zakhiwo ezifanayo zisho ukuthi ukuhambisana kwe-solvent, ukulawulwa komhwamuko kanye nezimo zokuthola kabusha kufanele kuhlolwe ngenqubo ngayinye.
I-THF isebenza njengendawo yokusabela, ukucubungula i-solvent kanye nesakhiwo samakhemikhali kuyo yonke i-polymer, imithi, i-coating kanye nokusebenza okukhethekile kwamakhemikhali.
I-THF iyisiphakeli esibalulekile sokukhiqiza i-polytetramethylene ether glycol, ebizwa nangokuthi i-PTMEG noma i-PTMG. I-PTMEG kamuva isetshenziselwa imicu ye-elastane, i-thermoplastic polyurethane, i-polyurethane elastomers nezinye izinto ezisebenza kahle kakhulu.
Ngezicelo zokukhiqiza i-polymer, abathengi bangahlola:
Ubumsulwa be-THF
Amanzi kanye ne-asidi
Okuqukethwe kokuqinisa
Ukuvumelana phakathi kwamaqoqo okukhiqiza
Ikhono lokupakisha nokudlulisa okuningi
Ukulandeleka nokuqhubeka kokunikezwa
I-THF isetshenziswa kabanzi njengendawo yokusabela yekhemikhali ye-organometallic ngoba umoya-mpilo wayo we-ether usiza ekuxazululeni izikhungo zensimbi. Ngokuvamile kuhlotshaniswa nama-reagents e-Grignard, ukuncishiswa, ukusabela kokuhlanganisa kanye nezinye izinguquko ezithinta umswakama.
Ukukhethwa kwebanga kufanele kusekelwe emanzini avunyelwe, isinzisi kanye nemikhawulo yokungcola. I-Anhydrous THF equkethe isizinzi ingase ifanelekele ukusabela okuthile, kuyilapho ezinye izinqubo zidinga ibanga elingenayo inhibitor.
I-THF ingancibilikisa noma iguqule i-viscosity yama-polymer akhethiwe kanye nezinhlelo ze-resin. Izicelo zifaka:
Osimende be-solvent ye-PVC
Okunamathelayo okukhethekile
Izembatho ze-polymer
Izixazululo ze-resin
Ukucubungula ifilimu nolwelwesi
Ukusakaza kwe-polymer kwesilinganiso selabhorethri
Abakhiqizi kufanele baqinisekise ukuhambisana kwe-substrate, izinga lokuhwamuka, izilawuli zokuchayeka kubasebenzi kanye nezidingo zendawo ze-VOC.
Ekwenziweni kwemithi kanye namakhemikhali amahle, i-THF ingasetshenziswa njengesixazululi sokusabela, indawo yokukhipha noma insiza yokucubungula.
Imibandela yokuthenga ebalulekile ingabandakanya:
Okuqukethwe kwamanzi okuchaziwe
Isimemezelo sokuzinzisa
Iphrofayili yokungcola
Ukulandeleka kwenqwaba
Isu lokulawula ukuncibilika kwensalela
Ukushintsha okulindelwe kwesaziso
Amadokhumenti okulawula nawomsuka
Ukusetshenziswa ekucutshungulweni kwemithi akubonisi ngokwako ukuthi umkhiqizo usezingeni lezemithi. Ibanga elidingekayo kufanele lifanelekele inqubo ethile kanye nemakethe.
I-THF ingase isetshenziswe ekuhlanzeni okulawulwayo, ekukhishweni nasezinqubweni zaselabhorethri ngenxa yokuqina kwayo okubanzi. Ngaphambi kokusetshenziswa, qinisekisa ukuhambisana kwezinto, umoya omncane, ukuphatha imfucuza kanye namandla okunqwabelana kwe-peroxide.
Isici sokukhetha |
I-THF eqinile |
I-THF engavimbeli |
Ukulawulwa kwe-peroxide |
I-Stabilizer ibambezela ukwakheka kwe-peroxide |
Idinga i-oxygen eqinile, izilawuli zokukhanya kanye nempahla |
Ukuqina kwesitoreji okujwayelekile |
Ifaneleka kangcono ekusabalaliseni okujwayelekile |
Kuzwela kakhulu kumlando wesitoreji nokubamba |
Ukuhambisana kokusabela |
I-BHT kufanele yamukeleke kule nqubo |
Kucatshangelwa lapho ama-inhibitors ephazamisa uhlelo lokusebenza |
Imfuneko yokuthenga |
Cacisa ubunikazi be-inhibitor nobubanzi |
Cacisa umkhawulo we-peroxide, okulindelwe amanzi kanye nokusingatha |
Izinhlelo zokusebenza ezijwayelekile |
I-solvent ejwayelekile yezimboni kanye ne-polymer processing |
I-synthesis ebucayi, i-catalyst noma izinhlelo zokusebenza zokuhlaziya |
I-THF ye-inhibitor-free akumele ikhethwe ngoba nje ibonakala iwumkhiqizo 'ohlanzekile'. Ibanga elilungile ngokobuchwepheshe yilelo elihlangabezana kokubili nezidingo zenqubo-ukusebenza kanye nokuphatha ngokuphephile.
I-THF ingenza ama-peroxides lapho evezwe umoya-mpilo, ikakhulukazi ngesikhathi sokugcina isikhathi eside noma lapho kusetshenziswa izinto ezingenazihibithi. Ama-peroxide angase agxile ngesikhathi sokuhwamuka noma ukucwiliswa emanzini.
Uhlelo lokuphatha lwe-THF oluqondene nesayithi kufanele lubhekane:
Idethi yokutholwa kanye nedethi yokuvula
Isimo sokuzinzisa
Isikhathi sokugcina nezinga lokushisa
Ukuchayeka emoyeni nasekukhanyeni
Imvamisa yokuhlola i-peroxide nendlela
Izinga eliphezulu elamukelekayo leperoxide
Ukwelashwa kwezinto ezindala, ezingaziwa noma ezigxilile
Imikhawulo ekufakweni kwe-distillation noma ukuhwamuka kuze kome
Izinqubo zokulahla imfucuza ezifanele
Ungayisebenzisi, udlulise, ugxilise ingqondo noma udilize i-THF endala enomlando wesitoreji ongaziwa kuze kube yilapho isihloliwe ngaphansi kwenqubo yokuphepha egunyaziwe.
Ngokuya ngebanga, ubuningi bokuthunyelwa kanye nendawo okuyiwa kuyo, i-THF ingase ihlinzekwe ngezigubhu ezifanele, iziqukathi eziphakathi nendawo, amathangi e-ISO noma izinto zokuthutha ngobuningi. Ukutholakala kwamaphakheji kwangempela kufanele kuqinisekiswe ngesikhathi sekhotheshini.
I-THF kufanele igcinwe:
Ezitsheni ezigunyaziwe, ezivalwe ngokuqinile
Endaweni epholile, eyomile futhi enomoya omuhle yokugcina amakhemikhali
Kude nokushisa, izinhlansi, amalangabi nezinto ezingahambelani ze-oxidizing
Ngezinyathelo ezifanele zokubopha, ukubeka phansi kanye nokulawula umhwamuko
Ngaphansi kwezimo ezivikela umkhiqizo emoyeni ongadingekile nokuchayeka ekukhanyeni
Ngokuhambisana ne-SDS yamanje yomphakeli kanye nemithetho yendawo
Qinisekisa ukuthi iphakheji ecashuniwe iyabuyiselwa yini, imbozwe nge-nitrogen noma ingaphansi kwezidingo ze-oda elincane.
I-THF iwuketshezi oluvutha kakhulu kanye nomhwamuko. Kungacasula amehlo nendlela yokuphefumula, futhi ukugcwala komhwamuko ophakeme kungathinta isimiso sezinzwa esimaphakathi. Umhwamuko wawo ungase uhambe uye emthonjeni wokuthungela bese ubuyela emuva.
Izilawuli ezijwayelekile zihlanganisa ukudlulisa okuvaliwe, ukungena komoya okusebenzayo, okokusebenza kukagesi okugunyaziwe, isilawuli somthombo wokuthungela, ibhondi kanye nokubeka phansi, okokuvikela komuntu siqu kanye nohlelo lokusabela ezimeni eziphuthumayo.
Okokuthutha, i-Tetrahydrofuran ivame ukukhonjwa ngokuthi:
Inombolo ye-UN: UN 2056
Igama elifanele lokuthumela: Tetrahydrofuran
Isigaba esiyingozi: 3
Iqembu lokupakisha: II
Leli khasi alithathi indawo Yedatha Yezokuphepha Yamanje. Hlala ulandela i-SDS, imithetho yezokuthutha esebenzayo kanye nezidingo zendawo zokuchayeka emsebenzini.
Ngokuya ngemakethe nesicelo, abathengi bangacela:
Isitifiketi Sokuhlaziya
Ishidi Ledatha Yezokuphepha
Ishidi Ledatha Yezobuchwepheshe
Ukucaciswa komkhiqizo
Isitatimende sezwe lemvelaphi
Ukulandeleka kwenqwaba
Isimemezelo sokuzinzisa
Isitatimende se-Allergen noma imvelaphi yezilwane lapho kufanele khona
REACH, TSCA noma olunye ulwazi lokulawula oluqondene nemakethe
Imininingwane yokupakisha nezokuthutha
Umgomo wokushintsha isaziso
Ukutholakala kwedokhumenti kanye nesimo sokulawula kufanele kuqinisekiswe izwe okuyiwa kulo ngaphambi koku-oda.
Ukuze uthole ikhotheshini esheshayo nenembe kakhulu, hlinzeka:
Igama lomkhiqizo kanye nenombolo ye-CAS
Ibanga elidingekayo
Ukuhlola okuncane
Ubuningi bokuqukethwe kwamanzi
Isidingo esizinzile noma esingena-inhibitor
Ububanzi obudingekayo be-BHT, uma bukhona
Umkhawulo ophezulu we-peroxide
Ukupakishwa okudingekayo
Oda inani kanye nesidingo sonyaka
Izwe lokulethwa, idolobha noma itheku
Isicelo esihlosiwe
Amadokhumenti noma izimfuneko zokulawula
I-Tetrahydrofuran iyi-ether ejikelezayo engenambala, engaxubeki emanzini esetshenziswa njengesixazululi sezinto eziphilayo, indawo yokusabela kanye nendawo yamakhemikhali. Inombolo yayo ye-CAS ngu-109-99-9.
I-THF iyinhlanganisela ephilayo. Ngokuqondile, iyi-ether equkethe umoya-mpilo, enamalungu amahlanu i-heterocyclic.
Kubili. I-THF isetshenziswa kabanzi njenge-solvent ne-reaction medium, kuyilapho amavolumu amakhulu abuye asetshenziswe njengendawo yamakhemikhali yokukhiqiza i-PTMEG.
Yebo. I-THF ixubene namanzi. Lesi sakhiwo singaba usizo ezinqubweni ezithile kodwa futhi sisho ukuthi ukulawula umswakama kubalulekile ekusetshenzisweni okungezwani namanzi.
I-Anhydrous ichaza okuqukethwe kwamanzi aphansi alawulwayo. I-inhibitor-free isho ukuthi asikho isiqinisi esifana ne-BHT esingezwe ngamabomu. Ibanga le-THF lingaba ne-anhydrous ngenkathi lisaqukethe isiqinisi.
I-BHT ijwayele ukungezwa ukuze kubambezeleke ukwakheka kwama-peroxides ngesikhathi sokugcinwa nokusabalalisa. Izinga le-BHT elidingekayo kufanele liqinisekiswe ngoba ukuqina kungase kuthinte ukusabela okuthile noma izindlela zokuhlaziya.
Yebo. I-THF ingakha ama-peroxides ayingozi ngesikhathi sokuchayeka kumoya-mpilo, ikakhulukazi ngesikhathi sokugcinwa isikhathi eside noma lapho ihlinzekwa ngaphandle kokuqiniswa. Ama-peroxides angaba yingozi kakhulu uma i-THF igxilile noma i-distilled.
Ibanga lamanzi aphansi noma i-anhydrous livame ukudingeka, kodwa amazinga avunyelwe ukuzinza kanye nokungcola ancike ku-reagent ethile kanye nenqubo. Abathengi kufanele bacacise amanzi amaningi nokuthi i-BHT yamukelekile yini.
I-CoA ewusizo ingase ibike ukuhlolwa, amanzi, umbala, i-asidi, okuqukethwe kwe-peroxide nokuqukethwe kokuqiniswa. Ukuhlolwa okwengeziwe kungavunyelwana ngezicelo zokuhlaziya, ezemithi noma ze-polymer.
Sithumelele i-THF yakho edingekayo, i-assay, umkhawulo wamanzi, imfuneko yokuqinisa, ukupakisha, ubuningi nendawo oya kuyo. Sizoqinisekisa ukucaciswa okusebenzayo, imibhalo, izinketho zokupakisha kanye nemibandela yokuthengisa yesicelo sakho.
Ukuze uthole ukuhlanganiswa okubucayi noma ukukhiqizwa kwe-polymer, faka amazinga akho aphezulu avunyelwe amanzi, i-BHT ne-peroxide ukuze izinga elifanele lihlolwe.